Study of palladium thioether complexes at high pressure
نویسندگان
چکیده
منابع مشابه
High-pressure studies of palladium and platinum thioether macrocyclic dihalide complexes.
The mononuclear macrocyclic Pd(II) complex cis-[PdCl2([9]aneS3)] ([9]aneS3 = 1,4,7-trithiacyclo-nonane) converts at 44 kbar into an intensely coloured chain polymer exhibiting distorted octahedral coordination at the metal centre and an unprecedented [1233] conformation for the thioether ligand. The evolution of an intramolecular axial sulfur-metal interaction and an intermolecular equatorial s...
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The mononuclear Pd(ii) complex cis-[PdCl(2)([9]aneS(3))]([9]aneS(3)= 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2011
ISSN: 0108-7673
DOI: 10.1107/s0108767311099004